400-900-4166

GHS危险说明

HAZARD AND PRECAUTIONARY STATEMENTS

Hazard Statements

(There are 72 individual and 17 combined Hazard statements)

Physical Hazards

H200 Unstable explosives.
H201 Explosive; mass explosion hazard.
H202 Explosive, severe projection hazard.
H203 Explosive; fire, blast or projection hazard.
H204 Fire or projection hazard.
H205 May mass explode in fire.
H220 Extremely flammable gas.
H221 Flammable gas.
H222 Extremely flammable aerosol.
H223 Flammable aerosol.
H224 Extremely flammable liquid and vapour.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H227 Combustible liquid.
H228 Flammable solid.
H240 Heating may cause an explosion.
H241 Heating may cause a fire or explosion.
H242 Heating may cause a fire.
H250 Catches fire spontaneously if exposed to air.
H251 Self-heating: may catch fire.
H252 Self-heating in large quantities; may catch fire.
H260 In contact with water releases flammable gases which may ignite spontaneously.
H261 In contact with water releases flammable gas.
H270 May cause or intensify fire; oxidizer.
H271 May cause fire or explosion; strong oxidizer.
H272 May intensify fire; oxidizer.
H280 Contains gas under pressure; may explode if heated.
H281 Contains refrigerated gas; may cause cryogenic burns or injury.
H290 May be corrosive to metals.


Environmental Hazards

H400 Very toxic to aquatic life.
H401 Toxic to aquatic life.
H402 Harmful to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.
H420 Harms public health and the environment by destroying ozone in the upper atmospere.


European Union Hazard Statements

EUH001 Explosive when dry.
EUH006 Explosive with or without contact with air.
EUH014 Reacts violently with water.
EUH018 In use may form flammable/explosive vapour-air mixture.
EUH018a In use may form explosive vapour-air mixture.
EUH018b In use may form flammable vapour-air mixture.
EUH019 May form explosive peroxides.
EUH029 Contact with water liberates toxic gas.
EUH030 Can become highly flammable in use.
EUH031 Contact with acids liberates toxic gas.
EUH032 Contact with acids liberates very toxic gas.
EUH044 Risk of explosion if heated under confinement.
EUH059 Hazardous to the ozone layer.
EUH066 Repeated exposure may cause skin dryness or cracking.
EUH070 Toxic by eye contact.
EUH071 Corrosive to the respiratory tract.
EUH201 Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. Warning! Contains lead.
EUH201A Warning! Contains lead.
EUH202 Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
EUH203 Contains chromium (VI). May produce an allergic reaction.
EUH204 Contains isocyanates. See information supplied by the manufacturer.
EUH205 Contains epoxy constituents. See information supplied by the manufacturer.
EUH206 Warning! Do not use together with other products. May release dangerous gases (chlorine).
EUH207 Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer.
Comply with the safety instructions.
EUH207-EG Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer.
Comply with the safety instructions.
EUH208 Contains (name of sensitising substance). May produce an allergic reaction.
EUH208-EG Contains (name of sensitising substance). May produce an allergic reaction.
EUH209 Can become highly flammable in use.
EUH209a Can become highly flammable in use.
EUH209b Can become flammable in use.
EUH209A Can become flammable in use.
EUH210 Safety data sheet available on request.
EUH401 To avoid risks to human health and the environment, comply with the instructions for use.


Precautionary Statements

(There are 116 individual and 33 combined Precautionary statements)


Precautionary statements - General

P101If medical advice is needed,have product container or label at hand.
P102Keep out of reach of children.
P103Read label before use


Precautionary statements - Prevention

P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P211Do not spray on an open flame or other ignition source.
P220Keep/Store away from clothing/…/combustible materials.
P221Take any precaution to avoid mixing with combustibles/…
P222Do not allow contact with air.
P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P230Keep wetted with …
P231Handle under inert gas.
P232Protect from moisture.
P233Keep container tightly closed.
P234Keep only in original container.
P235Keep cool.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
P244Keep reduction valves free from grease and oil.
P250Do not subject to grinding/shock/…/friction.
P251Pressurized container: Do not pierce or burn, even after use.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P262Do not get in eyes, on skin, or on clothing.
P263Avoid contact during pregnancy/while nursing.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P281Use personal protective equipment as required.
P282Wear cold insulating gloves/face shield/eye protection.
P283Wear fire/flame resistant/retardant clothing.
P284Wear respiratory protection.
P285In case of inadequate ventilation wear respiratory protection.
P231+P232Handle under inert gas. Protect from moisture.
P235+P410Keep cool. Protect from sunlight.


Precautionary statements - Response

P301IF SWALLOWED:
P304IF INHALED:
P305IF IN EYES:
P306IF ON CLOTHING:
P307IF exposed:
P308IF exposed or concerned:
P309IF exposed or if you feel unwell:
P310Immediately call a POISON CENTER or doctor/physician.
P311Call a POISON CENTER or doctor/physician.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P313Get medical advice/attention.
P314Get medical advice/attention if you feel unwell.
P315Get immediate medical advice/attention.
P320Specific treatment is urgent (see … on this label).
P321Specific treatment (see … on this label).
P322Specific measures (see …on this label).
P330Rinse mouth.
P331Do NOT induce vomiting.
P332IF SKIN irritation occurs:
P333If skin irritation or rash occurs:
P334Immerse in cool water/wrap n wet bandages.
P335Brush off loose particles from skin.
P336Thaw frosted parts with lukewarm water. Do not rub affected area.
P337If eye irritation persists:
P338Remove contact lenses, if present and easy to do. Continue rinsing.
P340Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342If experiencing respiratory symptoms:
P350Gently wash with plenty of soap and water.
P351Rinse cautiously with water for several minutes.
P352Wash with plenty of soap and water.
P353Rinse skin with water/shower.
P360Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361Remove/Take off immediately all contaminated clothing.
P362Take off contaminated clothing and wash before reuse.
P363Wash contaminated clothing before reuse.
P370In case of fire:
P371In case of major fire and large quantities:
P372Explosion risk in case of fire.
P373DO NOT fight fire when fire reaches explosives.
P374Fight fire with normal precautions from a reasonable distance.
P376Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378Use … for extinction.
P380Evacuate area.
P381Eliminate all ignition sources if safe to do so.
P390Absorb spillage to prevent material damage.
P391Collect spillage. Hazardous to the aquatic environment
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302+P350IF ON SKIN: Gently wash with plenty of soap and water.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P312IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304+P341IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338
P306+P360IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307+P311IF exposed: call a POISON CENTER or doctor/physician.
P308+P313IF exposed or concerned: Get medical advice/attention.
P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.
P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337+P313IF eye irritation persists: Get medical advice/attention.
P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370+P376in case of fire: Stop leak if safe to Do so.
P370+P378In case of fire: Use … for extinction.
P370+P380in case of fire: Evacuate area.
P370+P380+P375in case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371+P380+P375in case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.


Precautionary statements — Storage

P401Store …
P402Store in a dry place.
P403Store in a well-ventilated place.
P404Store in a closed container.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405Store locked up.
P406Store in corrosive resistant/… container with a resistant inner liner.
P407Maintain air gap between stacks/pallets.
P410Protect from sunlight.
P411Store at temperatures not exceeding … oC/…oF.
P412Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413Store bulk masses greater than … kg/…lbs at temperatures not exceeding … oC/…oF.
P420Store away from other materials.
P422Store contents under …
P402+P404Store in a dry place. Store in a closed container.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P403+P235Store in a well-ventilated place. Keep cool.
P410+P403Protect from sunlight. Store in a well-ventilated place.
P410+P412Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411+P235Store at temperatures not exceeding … oC/…oF. Keep cool.


Precautionary statements — Disposal

P501Dispose of contents/container to..…
P502Refer to manufacturer/supplier for information on recovery/recycling

PICTOGRAMS AND HAZARD CODES

Compared to the current EU system the most noticeable change are the pictograms (formerly: hazard symbols). While the most of the GHS pictograms
have an equivalent in the old system, the pictograms GHS 04, GHS 07 and GHS 08 are completely new.

The GHS System is built on 16 physical, 10 health and 3 environmental hazard classes and comprises the following communication elements:

9 Pictograms

Description Pictogram Hazard class and hazard category:
Exploding Bomb
GHS01
GHS01 Unstable explosives
Explosives of Divisions 1.1, 1.2, 1.3, 1.4
Self reactive substances and mixtures, Types A,B
Organic peroxides, Types A,B
Flame
GHS02
GHS02 Flammable gases, category 1
Flammable aerosols, categories 1,2
Flammable liquids, categories 1,2,3
Flammable solids, categories 1,2
Self-reactive substances and mixtures, Types B,C,D,E,F
Pyrophoric liquids, category 1
Pyrophoric solids, category 1
Self-heating substances and mixtures, categories 1,2
Substances and mixtures, which in contact with water,
emit flammable gases, categories 1,2,3
Organic peroxides, Types B,C,D,E,F
Flame Over Circle
GHS03
Oxidizing gases, category 1
Oxidizing liquids, categories 1,2,3
Gas Cylinder
GHS04
Gases under pressure:
- Compressed gases
- Liquefied gases
- Refrigerated liquefied gases
- Dissolved gases
Corrosion
GHS05
Corrosive to metals, category 1
Skin corrosion, categories 1A,1B,1C
Serious eye damage, category 1
Skull and Crossbones
GHS06
Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Exclamation Mark
GHS07
Acute toxicity (oral, dermal, inhalation), category 4
Skin irritation, category 2
Eye irritation, category 2
Skin sensitisation, category 1
Specific Target Organ Toxicity – Single exposure, category 3
Health Hazard
GHS08
Respiratory sensitization, category 1
Germ cell mutagenicity, categories 1A,1B,2
Carcinogenicity, categories 1A,1B,2
Reproductive toxicity, categories 1A,1B,2
Specific Target Organ Toxicity – Single exposure, categories 1,2
Specific Target Organ Toxicity – Repeated exposure, categories 1,2
Aspiration Hazard, category 1
Environment
GHS09
Hazardous to the aquatic environment
- Acute hazard, category1
- Chronic hazard, categories 1,2

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